Monday, October 13, 2014

Related attributes introduced of Tetrachlorosilane


was born in Bergamo in 1983. In 2007 he obtained his Laurea in Chemistry, at the University of Milan, Italy and in 2010 he completed his doctoral studies on the activation of trichlorosilyl derivatives with chiral Lewis bases under the supervision of Prof. Benaglia, at the University of Milan. In 2011, he joined the group of Prof. Denmark with a post-doctoral fellowship, at the University of Urbana-Champaign, USA, where he worked on the Lewis base-catalyzed asymmetric sulfenylation reactions. In 2012 he moved back to Milan, as postdoctoral fellow, where he is developing enantiomerically pure tetrachlorosilane-based Lewis acids for catalysis.
Physical Data:mp −70°C; bp 57.6°C; d 1.483 g cm−3.
Solubility:sol benzene, ether, chloroform, petroleum ether, dichloromethane.
Form Supplied in:neat as clear colorless liquid; as 1.0 M solution in dichloromethane.

Handling, Storage, and Precautions:the neat liquid and solutions react violently with water and protic solvents to produce HCl gas. The neat reagent reacts violently and/or explosively with DMSO and DMF. Avoid contact with metals, strong bases, strong acids, and glass. Corrosive; stench; handle and store under N2; store cool. Use in a fume hood.

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